刘永壮

所在单位:材料科学与工程学院

学历:博士研究生毕业

在职信息:在职

论文成果

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Efficient Cleavage of Strong Hydrogen Bonds in Cotton by Deep Eutectic Solvents and Facile Fabrication of Cellulose Nanocrystals in High Yields

发布时间:2017-07-20 点击次数:

影响因子:7.1
DOI码:10.1021/acssuschemeng.7b00954
所属单位:东北林业大学
发表刊物:ACS Sustainable Chemistry & Engineering
摘要:The content of cellulose in biomass is important for producing nanocellulose in high yield. Cotton fibers containing ultrahigh purity (~95%) cellulose are ideal feedstock for nanocellulose production. However, the presence of strong hydrogen bonding between the cellulose chains limits the use of cotton fibers for the production of nanocellulose in a facile and mild process. Here, efficient cleavage of the strong hydrogen bonds in cotton and ultrafast fabrication of cellulose nanocrystals (CNCs) with a high yield of 74.2% were first realized through 3-min microwave-assisted deep eutectic solvent pretreatment and a subsequent high-intensity ultrasonication process. The obtained CNCs had diameters of 3–25 nm and lengths ranged between 100 and 350 nm. The CNCs also displayed relative crystallinity of 82% and the thermal degradation temperature started from 320 °C. The study provides a green and efficient method for the mass production of cotton CNCs, and is expected to contribute to improving the refinery utilization of cotton feedstock.
合写作者:Bingtuo Guo,Qinqin Xia,Juan Meng,Wenshuai Chen,Shouxin Liu,Qingwen Wang,Yixing Liu,Jian Li
第一作者:Yongzhuang Liu
论文类型:期刊论文
通讯作者:Haipeng Yu
文献类型:J
卷号:5
期号:9
页面范围:7623-7631
是否译文:
发表时间:2017-01-01
收录刊物:SCI
发布期刊链接:https://pubs.acs.org/doi/10.1021/acssuschemeng.7b00954