个人信息Personal Information
教师拼音名称:liuyongzhuang
出生日期:1990-12-11
所在单位:材料科学与工程学院
学历:博士研究生毕业
性别:男
学位:工学博士学位
在职信息:在职
学科:木材科学与技术
Recyclable nanocellulose-confined palladium nanoparticles with enhanced room-temperature catalytic activity and chemoselectivity
点击次数:
影响因子:6.8
DOI码:10.1007/s40843-020-1438-9
所属单位:东北林业大学
发表刊物:Science China Materials
摘要:We describe the synthesis of even-dispersed palladium nanoparticles (Pd NPs) confined within a cellulose nanofiber (CNF) matrix for developing a high-performance and recyclable catalyst. The CNF matrix was composed of CNF-assembled mesoporous nanosheets and appeared as soft and hydrophilic foam. Ultrafine Pd NPs (∼6 nm) with high-loading (9.6 wt%) were in situ grown on these mesoporous nanosheets, and their dense spatial distributions were likely to generate nano-confinement catalytic effects on the reactants. Consequently, the CNF-confined Pd NPs (CNF-Pd) exhibited an enhanced room-temperature catalytic activity on the model reaction of 4-nitrophenol hydrogenation with a highest rate constant of 8.8×10⁻³ s⁻¹ and turnover frequency of 2640 h The CNF Pd catalyst possessed good chemical stability and recyclability in aqueous media which could be reused for at least six cycles without losing activity. Moreover, chemoselective reduction of 3 nitrostyrene was achieved with high yield (80%–98%) of 3-aminostyrene in alcohol/water cosolvent. Overall, this work demonstrates a positive nanoconfinement effect of CNFs for developing stable and recyclable metal NP catalysts.
合写作者:Xiaochao Shi,Wenshuai Chen
第一作者:Juan Meng,Yongzhuang Liu
论文类型:期刊论文
通讯作者:Xianquan Zhang,Haipeng Yu
文献类型:J
卷号:64
页面范围:621-630
是否译文:否
发表时间:2020-01-01
收录刊物:SCI
发布期刊链接:https://link.springer.com/article/10.1007/s40843-020-1438-9