个人信息Personal Information
教师拼音名称:liuyongzhuang
出生日期:1990-12-11
所在单位:材料科学与工程学院
学历:博士研究生毕业
性别:男
学位:工学博士学位
在职信息:在职
学科:木材科学与技术
Hydrogen-Transfer Reductive Catalytic Fractionation of Lignocellulose: High Monomeric Yield with Switchable Selectivity
点击次数:
影响因子:16.1
DOI码:10.1002/anie.202307116
所属单位:东北林业大学
发表刊物:Angewandte Chemie International Edition
摘要:Lignin solubilization and in situ hydrogenolysis are crucial for reductive catalytic fractionation (RCF) of lignocellulose to aromatic monomers. In this study, we reported a typical hydrogen bond acceptor of choline chloride (ChCl) to tailor the hydrogen-donating environment of the Ru/C-catalyzed hydrogen-transfer RCF of lignocellulose. The ChCl-tailored hydrogen-transfer RCF of lignocellulose was conducted under mild temperature and low-pressure (<1 bar) conditions, which was applicable to other lignocellulosic biomass sources. We obtained an approximate theoretical yield of propylphenol monomer of 59.2 wt % and selectivity of 97.3 % using an optimal content of ChCl (10 wt %) in ethylene glycol at 190 °C for 8 h. When the content of ChCl in ethylene glycol was increased to 110 wt %, the selectivity of propylphenol switched toward propylenephenol (yield of 36.2 wt % and selectivity of 87.6 %). The findings in this work provide valuable information for transforming lignin from lignocellulose into value-added products.
合写作者:Yanyan Yu,Yuhan Lou,Suqing Zeng,Yaxu Sun
第一作者:Yilin Li
论文类型:期刊论文
通讯作者:Yongzhuang Liu,Haipeng Yu
文献类型:J
卷号:62
期号:32
页面范围:e202307116
是否译文:否
发表时间:2023-01-01
收录刊物:SCI
发布期刊链接:https://onlinelibrary-wiley-com-443.webvpn.nefu.edu.cn/doi/10.1002/anie.202307116